Научные интересы

Разработка новых методологий синтеза высокофункционализированных N-, N,O- и N,N-гетероциклов на основе:

• 2Н-азиринов;
• азаполиеновых соединений;
• родиевых и медных карбеноидов и нитреноидов.

Награды и премии

• 2023 – Премия имени Б. Б. Пиотровского СПбГУ "За проведение реставрационной работы бюста академика А. Е. Фаворского" (совместно с М.А. Кинжаловым и М.А. Кузнецовой)
• 2016 — Премия СПбГУ «За научные труды» в номинации «За фундаментальные достижения в науке» (совместно с Н. А. Бокач, В. А. Рассадиным и Д. С. Болотиным)
• 2016 — Премия СПбГУ «За научные труды» в номинации «За фундаментальные достижения в науке»
• 2012 — Победитель конкурса грантов для аспирантов вузов, расположенных на территории Санкт-Петербурга
• 2012 — Дипломы I степени за лучший устный доклад на VI Всероссийская конференция молодых учёных, аспирантов и студентов с международным участием "Менделеев-2012"
• 2011 — Победитель конкурса научных работ молодых учёных и аспирантов Химического факультета СПбГУ им. Н.А. Меншуткина
• 2011— Диплом II степени за лучший устный доклад на конференции «V Международный симпозиум «Химия алифатических диазосоединений: достижения и перспективы»
• 2010 — Дипломы I степени за лучший устный доклад на Всероссийской молодёжной конференции-школе «Идеи и наследие А. Е. Фаворского в органической и металлоорганической химии XXI века»
• 2009/2010 — Стипендия Президента Российской Федерации
• 2009 — Дипломы I степени за лучший устный доклад на международной конференции «Основные тенденции развития химии в начале XXI-го века»
• 2008/2009 — Стипендия фирмы «Chembridge»
• 2005/2006 — Стипендия Губернатора Ленинградской области

Публикации

1. Novikov M. S., Rostovskii N. V. Transannulations of N-Sulfonyl-1,2,3-triazoles with Carbo/Heterocycles (chapter 4 in Book «Denitrogenative Transformation of Nitrogen Heterocycles», 2025, Wiley‐VCH GmbH), P. 83-114. DOI: 10.1002/9783527844852.ch4
2. Golubev A. A., Simdianov I. V., Smetanin I. A., Agafonova A. V., Rostovskii N. V., Khlebnikov A. F., Novikov M. S. 2-Azidoazirines suitable for click chemistry: synthesis of 1-(2H-azirin-2-yl)-1H-1,2,3-triazoles. New J. Chem. 2024, 48, 19957-19962. DOI: 10.1039/D4NJ03517H
3. Stoikov I. I., Antipin I. S., Burilov V. A., Kurbangalieva A. R., Rostovskii N. V., Pankova A. S., Balova I. A., Remizov Yu. O., Pevzner L. M., Petrov M. L., Vasilyev A. V., Averin A. D., Beletskaya I. P., Nenajdenko V. G., Beloglazkina E. K., Gromov S. P., Karlov S. S., Magdesieva T. V., Prishchenko A. A., Popkov S. V., Terent’ev A. O., Tsaplin G. V., Kustova T. P., Kochetova L. B., Magdalinova N. A., Krasnokutskaya E. A., Nyuchev A. V., Kuznetsova Yu. L., Fedorov A. Yu., Egorova A. Yu., Grinev V. S., Sorokin V. V., Ovchinnikov K. L., Kofanov E. R., Kolobov A. V., Rusinov V. L., Zyryanov G. V., Nosov E. V., Bakulev V. A., Belskaya N. P., Berezkina T. V., Obydennov D. L., Sosnovskikh V. Ya., Bakhtin S. G., Baranova O. V., Doroshkevich V. S., Raskildina G. Z., Sultanova R. M., Zlotskii S. S., Dyachenko V. D., Dyachenko I. V., Fisyuk A. S., Konshin V. V., Dotsenko V. V., Ivleva E. A., Reznikov A. N., Klimochkin Yu. N., Aksenov D. A., Aksenov N. A., Aksenov A. V., Burmistrov V. V., Butov G. M., Novakov I. A., Shikhaliev Kh. S., Stolpovskaya N. V., Medvedev S. M., Kandalintseva N. V., Prosenko O. I., Menshchikova E. B., Golovanov A. A., Khashirova S. Yu. Organic Chemistry in Russian Universities. Achievements of Recent Years. Russ. J. Org. Chem. 2024, 60, 1361–1584. DOI: 10.1134/s1070428024080013
4. Filippov I.P., Zakharov T.N., Grishin A.V., Khlebnikov A.F., Novikov M.S., Rostovskii N.V. DBU-Promoted Cyclizations of Cyclopentyl-Substituted Oxazapolyenes to Cyclopentapyridones and Hydroxypyrroles: Experimental and DFT Study. J. Org. Chem. 2024, 89, 15404–15413. DOI: 10.1021/acs.joc.4c00647
5. Titov G.D., Bunev A.S., Urusova S.V., Novikov M.S., Khlebnikov A.F., Rostovskii N.V. Rhodium-Catalyzed Double Dearomatization of 1,2,3-Triazole−Isoxazole Dyads: Synthesis of Nonfused 1H‑1,3-Diazepines. Org. Lett. 2024, 26, 7828−7833. DOI: 10.1021/acs.orglett.4c02588
6. Karpov I. D., Kolobov A. V., Filippov I. P., Rostovskii N. V., Ovchinnikov K. L. A one-pot synthesis of 3-nitro-2H-thiopyrans and their selective reduction to 3-nitro-3,4-dihydro-2H-thiopyrans. Chem. Heterocycl. Compd. 2024, 60, 251–256. DOI: 10.1007/s10593-024-03329-9
7. Charushin, V. N., Verbitskiy, E. V., Chupakhin, O. N., Vorobyeva, D. V., Gribanov, P. S., Osipov, S. N., Ivanov, A. V., Martynovskaya, S. V., Sagitova, E. F., Dyachenko, V. D., Dyachenko, I. V., Krivokolylsko, S. G., Dotsenko, V. V., Aksenov, A. V., Aksenov, D. A., Aksenov, N. A., Larin, A. A., Fershtat, L. L., Muzalevskiy, V. M., Nenajdenko, V. G., Gulevskaya, A. V., Pozharskii, A. F., Filatova, E. A., Belyaeva, K. V., Trofimov, B. A., Balova, I. A., Danilkina, N. A., Govdi, A. I., Tikhomirov, A. S., Shchekotikhin, A. E., Novikov, M. S., Rostovskii, N. V., Khlebnikov, A. F., Klimochkin, Y. N., Leonova, M. V., Tkachenko, I. M., Mamedov, V. A. O., Mamedova, V. L., Zhukova, N. A., Semenov, V. E., Sinyashin, O. G., Borshchev, O. V., Luponosov, Y. N., Ponomarenko, S. A., Fisyuk, A. S., Kostyuchenko, A. S., Ilkin, V. G., Beryozkina, T. V., Bakulev, V. A., Gazizov, A. S., Zagidullin, A. A., Karasik, A. A., Kukushkin, M. E., Beloglazkina, E. K., Golantsov, N. E., Festa, A. A., Voskresenskii, L. G., Moshkin, V. S., Buev, E. M., Sosnovskikh, V. Y., Mironova, I. A., Postnikov, P. S., Zhdankin, V. V., Yusubov, M. S. O., Yaremenko, I. A., Vil', V. A., Krylov, I. B., Terent'ev, A. O., Gorbunova, Y. G., Martynov, A. G., Tsivadze, A. Y., Stuzhin, P. A., Ivanova, S. S., Koifman, O. I., Burov, O. N., Kletskii, M. E., Kurbatov, S. V., Yarovaya, O. I., Volcho, K. P., Salakhutdinov, N. F., Panova, M. A., Burgart, Y. V., Saloutin, V. I., Sitdikova, A. R., Shchegravina, E. S., Fedorov, A. Y. The chemistry of heterocycles in the 21st century. Russ. Chem. Rev. 2024, 93, RCR5125. DOI: 10.59761/RCR5125
8. Titov G.D., Rostovskii N.V. (1RS,3SR)-1-(4-Methylbenzyl)-7-phenyl-5-oxa-6-azaspiro[2.4]hept-6-en-4-one. MolBank 2024, 2024, M1799. DOI: 10.3390/M1799
9. Grishin A. V., Filippov I. P., Rostovskii N. V. Synthesis, Structure, and Properties of Rhodium(II) Acetate Complexes with 2H-Azirines. Russ. J. Gen. Chem. 2024, 94, S47–S52. DOI: 10.1134/S107036322414007X
10. Efremova M. M., Rostovskii N. V. Symposium on the Chemistry of Alkynes, Allenes, and Small Rings. Russ. J. Org. Chem. 2023, 12, 2015-2037. DOI: 10.1134/S1070428023120011
11. Vasilchenko, D.S., Novikov, M.S., Rostovskii, N.V. Rh(II)-catalyzed and non-catalytic synthesis of (Z)-ethene-1,2-diamines from 1-tosyl-1,2,3-triazoles and primary anilines. Chem. Heterocycl. Compd. 2023, 59, 666-671. DOI: 10.1007/s10593-023-03252-5
12. Pankova, A.S., Golubev, P., Molin, I.A., Rostovskii, N.V. Regioselective Synthesis of 2-Trimethylsilyl-4H-pyran-4-ones from 1-Ethoxy(hydroxy)-5-(trimethylsilyl)pentenynones. Eur. J. Org. Chem. 2023, 26, e202300573. DOI: 10.1002/ejoc.202300573
13. Vasilchenko, D.S., Agafonova, A.V., Simdianov, I.V., Koronatov, A. N., Sakharov, P.A., Romanenko, I. A., Rostovskii, N.V., Khlebnikov, A.F., Novikov, M.S. 2H-1,2,3-triazole-4-carboxylic acids via Ru(II)-catalyzed rearrangement of 4-hydrazonoisoxazol-5-ones. Tetrahedron Lett. 2023, 123, 154580. DOI: 10.1016/j.tetlet.2023.154580
14. Zakharov, T.N., Sakharov, P.A., Novikov, M.S., Khlebnikov, A.F., Rostovskii, N.V. Triethylamine-Promoted Oxidative Cyclodimerization of 2H-Azirine-2-carboxylates to Pyrimidine-4,6-dicarboxylates: Experimental and DFT Study. Molecules 2023, 28, 4315. DOI: 10.3390/molecules28114315
15. Titov, G.D., Antonychev, G.I., Novikov, M.S., Khlebnikov, A.F., Rogacheva, E. V., Kraeva, L.A., Rostovskii, N.V. Gold vs Light: Chemodivergent Reactivity of Diazoesters toward 2H-Azirine-2-carboxylic Acids. Org. Lett. 2023, 25, 2707–2712. DOI: 10.1021/acs.orglett.3c00823
16. Strashkov, D.M., Zavyalov, K.V., Sakharov, P.A., ...Khlebnikov, A.F., Novikov, M.S. Rhodium-catalyzed migrative annulation and olefination of 2-aroylpyrroles with diazoesters. Org. Chem. Front. 2022, 10, 506–513. DOI: 10.1039/D2QO01759H
17. Karcev, D.D., Efremova, M.M., Molchanov, A.P., ...Bunev, A.S., Khochenkov, D.A. Selective and Reversible 1,3-Dipolar Cycloaddition of 2-(2-Oxoindoline-3-ylidene)acetates with Nitrones in the Synthesis of Functionalized Spiroisoxazolidines. Int. J. Mol. Sci. 2022, 23, 12639. DOI: 10.3390/ijms232012639
18. Sakharov, P.A.; Rostovskii, N.V.; Khlebnikov, A.F.; Novikov, M.S. Copper(II)-Catalyzed (3+2) Cycloaddition of 2H-Azirines to Six-Membered Cyclic Enols as a Route to Pyrrolo[3,2-c]quinolone, Chromeno[3,4-b]pyrrole, and Naphtho[1,8-ef]indole Scaffolds. Molecules 2022, 27, 5681, doi: 10.3390/molecules27175681
19. Shcherbakov, N.V.; Titov, G.D.; Chikunova, E.I.; Filippov, I.P.; Rostovskii, N.V.; Kukushkin, V.Y.; Dubovtsev, A.Y. Modular approach to non-aromatic and aromatic pyrroles through gold-catalyzed [3 + 2] cycloaddition of 2H-azirines and ynamides. Org. Chem. Front. 2022, 9, 5133–5140, doi: 10.1039/d2qo01105k
20. Filippov, I.P.; Novikov, M.S.; Khlebnikov, A.F.; Rostovskii, N.V. One-Pot Synthesis of Multifunctionalized 1-Pyrrolines from 2-Alkyl-2H-azirines and Diazocarbonyl Compounds. J. Org. Chem. 2022, 87, 8835–8840, doi: 10.1021/acs.joc.2c00977
21. Agafonova, A.V.; Sakharov, P.A.; Smetanin, I.A.; Rostovskii, N.V.; Khlebnikov, A.F.; Novikov, M.S. Stannyl radical-mediated synthesis of 6H-1,3-oxazin-6-ones from 2-acyloxyazirines or whether free radicals can open the azirine ring? Org. Chem. Front. 2022, 9, 4118–4127, doi: 10.1039/d2qo00783e
22. Filippov, I.P.; Agafonova, A.V.; Titov, G.D.; Smetanin, I.A.; Rostovskii, N.V.; Khlebnikov, A.F.; Novikov, M.S. Synthesis of Imidazo[1,2-a]pyridines via Near UV Light-Induced Cyclization of Azirinylpyridinium Salts. J. Org. Chem. 2022, 87, 6514–6519, doi: 10.1021/acs.joc.2c00514
23. Sakharov, P.A.; Novikov, M.S.; Nguyen, T.K.; Kinzhalov, M.A.; Khlebnikov, A.F.; Rostovskii, N.V. Blue Light-Promoted Cross-Coupling of α-Diazo Esters with Isocyanides: Synthesis of Ester-Functionalized Ketenimines. ACS Omega 2022, 7, 9071–9079, doi: 10.1021/acsomega.2c00367
24. Efremova, M.M.; Rostovskii, N.V. The VIth International Symposium “The Chemistry of Diazo Compounds and Related Systems” (DIAZO 2021). Russ. J. Org. Chem. 2022, 58, 335–351, doi: 10.1134/S1070428022030113
25. Agafonova A. V., Smetanin I. A., Rostovskii N. V., Khlebnikov A. F., Novikov M. S., Synthesis of 2-(2-Pyridyl)-2H-azirines via Metal-Free C–C Cross-Coupling of Bromoazirines with 2-Stannylpyridines. Org. Lett. 2021, DOI: 10.1021/acs.orglett.1c03060
26. Rostovskii N. V., Novikov M. S., Khlebnikov A. F., Electrocyclizations of Conjugated Azapolyenes Produced in Reactions of Azaheterocycles with Metal Carbenes. Organics 2021, 2, 313–336. DOI: 10.3390/org2030017
27. Tiuftiakov N. Y., Strelnikova J. O., Filippov I. P., Khaidarov A. R., Khlebnikov A. F., Bunev A. S., Novikov M. S., Rostovskii N. V., Rhodium-Catalyzed Synthesis of 2-Aroylpyrimidines via Cascade Heteropolyene Rearrangement. Org. Lett. 2021, 23, 6998–7002. DOI: 10.1021/acs.orglett.1c02706
28. Golubev A. A., Agafonova A. V., Smetanin I. A., Rostovskii N. V., Khlebnikov A. F., Bunev A. S., Novikov M. S., A Hydroxypyrrole Approach to 2,2′-Bi(4-pyrrolin-3-ones) and Pyrrolone-Based α-Amino Esters. J. Org. Chem. 2021, 86, 10368–10379. DOI: 10.1021/acs.joc.1c01070
29. Strelnikova J. O., Koronatov A. N., Rostovskii N. V., Khlebnikov A. F., Khoroshilova O. V., Kryukova, M. A., Novikov M. S., Rhodium-Catalyzed Denitrogenative Diazole-Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands. Org. Lett. 2021, 23, 4173–4178. DOI: 10.1021/acs.orglett.1c01092
30. Sakharov P. А., Novikov M. S., Rostovskii N. V., 2H-Azirines in medicinal chemistry. Chem. Heterocycl. Compd. 2021, 57, 512–521. DOI: 10.1007/s10593-021-02934-2
31. Koronatov A. N., Afanaseva K. K., Sakharov P. A., Rostovskii N. V., Khlebnikov A. F., Novikov M. S., Rh(II)-Catalyzed denitrogenative 1-sulfonyl-1,2,3-Triazole-1-Alkyl-1,2,3-Triazole cross-coupling as a route to 3-sulfonamido-1H-pyrroles and 1,2,3-Triazol-3-ium ylides. Org. Chem. Front. 2021, 8, 1474–1481. DOI: 10.1039/D0QO01571G
32. Strelnikova J. O., Rostovskii N. V., Khoroshilova O. V., Khlebnikov A. F., Novikov M. S., An Efficient Synthesis of Functionalized 2H-1,3,5-Oxadiazines via Metal-Carbenoid-Induced 1,2,4-Oxadiazole Ring Cleavage. Synthesis 2021, 53, 348–358. DOI: 10.1055/s-0040-1707278
33. Rostovskii N. V., Koronatov A. N., Sakharov P. A., Agafonova A. V., Novikov M. S., Khlebnikov A. F., Rogacheva E. V., Kraeva L. A., Azirine-containing dipeptides and depsipeptides: synthesis, transformations and antibacterial activity. Org. Biomol. Chem. 2020, 18, 9448–9460. DOI: 10.1039/d0ob02023k
34. Koronatov A. N., Rostovskii N. V., Khlebnikov A. F., Novikov M. S., Synthesis of 3-Alkoxy-4-Pyrrolin-2-ones via Rhodium(II)-Catalyzed Denitrogenative Transannulation of 1H-1,2,3-Triazoles with Diazo Esters. Org. Lett. 2020, 22, 7958–7963. DOI: 10.1021/acs.orglett.0c02893
35. Filippov I. P., Titov G. D., Rostovskii N. V., Recent Advances in Denitrogenative Reactions of Pyridotriazoles. Synthesis 2020, 52, 3564–3576. DOI: 10.1055/s-0040-1707254
36. Rostovskii N. V., Smetanin I. A., Koronatov A. N., Agafonova A. V., Potapenkov V. V., Khlebnikov A. F., Novikov M. S., Acid-catalyzed rearrangement of 1-acyl-2-azabuta-1,3-dienes to 4-pyrrolin-2-ones. Chem. Heterocycl. Compd. 2020, 56, 881–887. DOI: 10.1007/s10593-020-02745-x
37. Nguyen T. K., Titov G. D., Khoroshilova O. V., Kinzhalov M. A., Rostovskii N. V., Light-induced one-pot synthesis of pyrimidine derivatives from vinyl azides. Org. Biomol. Chem. 2020, 18, 4971–4982. DOI: 10.1039/D0OB00693A.
38. Sakharov P. A., Rostovskii N. V., Khlebnikov A. F., Novikov M. S., Regiodivergent Synthesis of Butenolide-Based α- And β-Amino Acid Derivatives via Base-Controlled Azirine Ring Expansion. Org. Lett. 2020, 22, 3023−3027. DOI: 10.1021/acs.orglett.0c00793.
39. Filippov I. P., Novikov M. S., Khlebnikov A. F., Rostovskii N. V., Pseudopericyclic Dearomative 1,6-Cyclization of 1-(2-Pyridyl)-2-azabuta-1,3-dienes: Synthesis and Ring–Chain Valence Equilibria of 4H-Pyrido[1,2-a]pyrazines. Eur. J. Org. Chem. 2020, 2020, 3688−3698. DOI: 10.1002/ejoc.202000210
40. I.A. Smetanin, A.V. Agafonova, N.V. Rostovskii, A.F. Khlebnikov, D.S. Yufit, M.S. Novikov Stereoselective assembly of 3,4-epoxypyrrolines via nucleophilic addition induced domino cyclization of 6-halo-1-oxa-4-azahexatrienes. Org. Chem. Front., 2020, 7, 525-530. DOI: 10.1039/C9QO01401B
41. P.A. Sakharov, A.N. Koronatov, A.F. Khlebnikov, M.S. Novikov, A.G. Glukharev, E.V. Rogacheva, L.A. Kraeva, V.V. Sharoyko, T.B. Tennikova, N.V. Rostovskii Non-natural 2H-azirine-2-carboxylic acids: anexpedient synthesis and antimicrobial activity, RSC Adv., 2019, 9, 37901-37905. DOI: 10.1039/C9RA09345A
42. A.N. Koronatov, N.V. Rostovskii, A.F. Khlebnikov, M.S. Novikov One-pot synthesis of 3-(pyridin-2-yl)-2,3-dihydroazetes via Rh(II)-catalyzed reaction of diazoesters with trimethylsilyl-protected 2-(pyridin-2-yl)-2H-azirines. Chem. Heterocycl. Compd. 2019, 55, 1185–1189. DOI: 10.1007/s10593-019-02599-y
43. A.V. Agafonova, I.A. Smetanin, N.V. Rostovskii, A.F. Khlebnikov, M.S. Novikov Easy Access to 2-Fluoro- and 2-Iodo-2H-azirines via the Halex Reaction. Synthesis 2019, 51, 4582-4589. DOI: 10.1055/s-0039-1690200
44. A.A. Golubev, I.A. Smetanin, A.V. Agafonova, N.V. Rostovskii, A.F. Khlebnikov, G.L. Starova, M.S. Novikov [2 + 1 + 1] Assembly of spiro β-lactams by Rh(ii)-catalyzed reaction of diazocarbonyl compounds with azirines/isoxazoles. Org. Biomol. Chem., 2019, 17, 6821-6830. DOI: 10.1039/C9OB01301F
45. P.A. Sakharov, N.V. Rostovskii, A.F. Khlebnikov, O.V. Khoroshilova, M.S. Novikov Transition Metal‐Catalyzed Synthesis of 3‐Coumaranone‐Containing NH‐Aziridines from 2H‐Azirines: Nickel(II) versus Gold(I). Adv. Synth. Catal. 2019, DOI: 10.1002/adsc.201900366
46. P.A. Sakharov, N.V. Rostovskii, A.F. Khlebnikov, T.L. Panikorovskii, M.S. Novikov 2H‑Azirines as C−C Annulation Reagents in Cu-Catalyzed Synthesis of Furo[3,2‑c]quinolone Derivatives. Org. Lett. 2019, 21, 3615–3619. DOI: 10.1021/acs.orglett.9b01043
47. A.R. Khaidarov, N.V. Rostovskii, A.A. Zolotarev, A.F. Khlebnikov, M.S. Novikov Synthesis of 1-(2-Aminovinyl)indoles and 1,3′-Biindoles by Reaction of 2,2-Diaryl-Substituted 2H-Azirines with α-Imino Rh(II) Carbenoids. J. Org. Chem. 2019, 84, 3743–3753. DOI: 10.1021/acs.joc.8b03205
48. A.F. Khlebnikov, M.S. Novikov, N.V. Rostovskii Advances in 2H-azirine chemistry: A seven-year update. Tetrahedron 2019, 75, 2555−2624. DOI: 10.1016/j.tet.2019.03.040
49. A. R. Khaidarov, N. V. Rostovskii, G. L. Starova, A. F. Khlebnikov, M. S. Novikov Synthesis of spirocyclic 3Н-pyrrol-4-amines from 2H-azirines and 1-sulfonyl-1,2,3-triazoles. Chem. Heterocycl. Compd. 2018, 54, 946–950. DOI: 10.1007/s10593-018-2378-8
50. A. V. Agafonova, N. V. Rostovskii, I. A. Smetanin, G. L. Starova, A. F. Khlebnikov, M. S. Novikov Synthesis of 2-(Di/tri/tetraazolyl)-2H-azirine-2-carboxylates by Halogen Substitution: Evidence for an SN2′-SN2′ Cascade Mechanism. J. Org. Chem., 2018, 83, 13473–13480. DOI: 10.1021/acs.joc.8b02295
51. A. V. Agafonova, I. A. Smetanin, N. V. Rostovskii, A. F. Khlebnikov, M. S. Novikov Expedient synthesis of 3-hydroxypyrroles via Bu₃SnH-triggered ionic 5-exo-trig-cyclization of 5-chloro-3-azamuconoate derivatives. Org. Chem. Front., 2018, 5, 3396–3401. DOI: 10.1039/c8qo00982a
52. J. O. Strelnikova, N. V. Rostovskii, G. L. Starova, A. F. Khlebnikov, M. S. Novikov Rh(II)-Catalyzed Transannulation of 1,2,4-Oxadiazole Derivatives with 1-Sulfonyl-1,2,3-triazoles: Regioselective Synthesis of 5-Sulfonamidoimidazoles. J. Org. Chem., 2018, 83, 11232–11244. DOI: 10.1021/acs.joc.8b01809
53. A. N. Koronatov, N. V. Rostovskii, A. F. Khlebnikov, M. S. Novikov Rh(II)-Catalyzed Ring Expansion of Pyrazoles with Diazocarbonyl Compounds as a Method for the Preparation of 1,2-Dihydropyrimidines. J. Org. Chem. 2018, 83, 9210–9219. DOI: 10.1021/acs.joc.8b01228
54. N. V. Rostovskii, I. A. Smetanin, A. V. Agafonova, P. A. Sakharov, J. O. Ruvinskaya, A. F. Khlebnikov, M. S. Novikov Facile access to 2-acyloxy-, aryloxy- and alkenyloxy-2H-azirines via an S_N2′–S_N2′ cascade in 2-halo-2H-azirines. Org. Biomol. Chem. 2018, 16, 3248–3257. DOI: 10.1039/C8OB00553B
55. J. O. Ruvinskaya, N. V. Rostovskii, I. P. Filippov, A. F. Khlebnikov, M. S. Novikov A novel approach to 5H-pyrazino[2,3-b]indoles via annulation of 3-diazoindolin-2-imines with 2H-azirines or 5-alkoxyisoxazoles under Rh(II) catalysis. Org. Biomol. Chem. 2018, 16, 38–42. DOI: 10.1039/c7ob02637d
56. M. S. Novikov, N. V. Rostovskii, A. N. Koronatov, K. V. Zavyalov, G. V. Zubakin, A. F. Khlebnikov, G. L. Starova Synthesis of 1,2-Dihydropyrimidine-2-carboxylates via Regioselective Addition of Rhodium(II) Carbenoids to 2H-Azirine-2-carbaldimines. J. Org. Chem. 2017, 82, 13396−13404. DOI: 10.1021/acs.joc.7b02484
57. A.V. Agafonova, I. A. Smetanin, N. V. Rostovskii, A. F. Khlebnikov, M. S. Novikov Synthesis of 2-halo-2Н-azirine-2-carboxylic acid amides and esters by isomerization of 5-(dialkylamino/alkoxy)-substituted isoxazoles, catalyzed by iron(II) sulfate. Chem. Heterocycl. Comp. 2017, 53, 1068–1071. DOI: 10.1007/s10593-017-2172-z
58. N. V. Rostovskii, M. S. Novikov, A. F. Khlebnikov, D. S. Yufit Two-atom azirine ring expansion reaction of methyl 2-diazo-3-(4-methoxyphenyl)-3-oxopropanoate via a dirhodium tetraacetatecatalyzed Wolff rearrangement. Chem. Heterocycl. Comp. 2017, 53, 985–988. DOI: 10.1007/s10593-017-2160-3
59. K. V. Zavyalov, M. S. Novikov, А. F. Khlebnikov, N. V. Rostovskii, G. L. Starova Rh₂(OAc)₄-Сatalyzed Reaction of 2-(2-Carbonylvinyl)-3-phenyl-2Н-azirines with Diazo Esters. Russ. J. Org. Chem. 2017, 53, 1214–1221. DOI: 10.1134/S1070428017080097
60. N. V. Rostovskii, A. V. Agafonova, I. A. Smetanin, M. S. Novikov, A. F. Khlebnikov, J. O. Ruvinskaya, G. L. Starova Metal-Catalyzed Isomerization of 5-Heteroatom-Substituted Isoxazoles as a New Route to 2-Halo-2H-azirines. Synthesis 2017, 49, 4478–4488. DOI: 10.1055/s-0036-1590822
61. P. A. Sakharov, N. V. Rostovskii, A. F. Khlebnikov, M. S. Novikov Annulation of five-membered cyclic enols with 3-aryl-2H-azirines: Catalytic versus non-catalytic cycloaddition. Tetrahedron 2017, 73, 4663–4670. DOI: 10.1016/j.tet.2017.06.037
62. A. A. Melekhova, A. S. Novikov, N. V. Rostovskii, P. A. Sakharov, T. L. Panikorovskii, N. A. Bokach Open-chain hemiketal is stabilized by coordination to a copper (II). Inorg. Chem. Commun. 2017, 79, 82–85. DOI: 10.1016/j.inoche.2017.03.024
63. N. V. Rostovskii, J. O. Ruvinskaya, M. S. Novikov, A. F. Khlebnikov, I. A. Smetanin, A. V. Agafonova Switchable Synthesis of Pyrroles and Pyrazines via Rh(II)-Catalyzed Reaction of 1,2,3-Triazoles with Isoxazoles: Experimental and DFT Evidence for the 1,4-Diazahexatriene Intermediate. J. Org. Chem. 2017, 82, 256−268. DOI: 10.1021/acs.joc.6b02389
64. K.V. Zavyalov, M.S. Novikov, A.F. Khlebnikov, N.V. Rostovskii (3Z)-2-Azahexa-1,3,5-trienes: Generation and Regioselectivity of 1,5- and 1,6-Cyclizations. Russ. J. Org. Chem. 2016, 52, 1851–1853. DOI: 10.1134/S1070428016120265
65. I. A. Smetanin, M. S. Novikov, A. V. Agafonova, N. V. Rostovskii, A. F. Khlebnikov, I. V. Kudryavtsev, M. A. Terpilowski, M. K. Serebriakova, A. S. Trulioff, N. V. Goncharov. A novel strategy for the synthesis of thermally stable and apoptosis-inducing 2,3-dihydroazetes. Org. Biomol. Chem. 2016, 14, 4479–4487. DOI: 10.1039/C6OB00588H
66. M. S. Novikov, A. F. Khlebnikov, N. V. Rostovskii, S. Tcyrulnikov, A. A. Suhanova, K. V. Zavyalov, D. S. Yufit. Pseudopericyclic 1,5- versus pericyclic 1,4- and 1,6-electrocyclization in electron-poor 4-aryl-2-azabuta-1,3-dienes. Indole synthesis from 2H-azirines and diazo compounds. J. Org. Chem. 2015, 80, 18–29. DOI: 10.1021/jo501051n
67. N. V. Rostovskii, M. S. Novikov, A. F. Khlebnikov, G. L. Starova, M. S. Avdontseva. Azirinium ylides from α-diazoketones and 2H-azirines on the route to 2H-1,4-oxazines: three-membered ring opening vs 1,5-cyclization. Beilstein J. Org. Chem. 2015, 11, 302–312. DOI: 10.3762/bjoc.11.35
68. A. V. Galenko, A. F. Khlebnikov, M. S. Novikov, V. V. Pakalnis, N. V. Rostovskii. Recent advances in isoxazole chemistry. Russ. Chem. Rev. 2015, 84, 335–377. DOI: 10.1070/RCR4503
69. I. A. Smetanin, M. S. Novikov, N. V. Rostovskii, A. F. Khlebnikov, G. L. Starova, D. S. Yufit. 4-Halo-2-azabuta-1,3-dienes as intermediates in the rhodium carbenoid-initiated transformation of 2-halo-2H-azirines into 2,3-dihydroazetes and 2,5-dihydrooxazoles. Tetrahedron 2015, 71, 4616–4628. DOI: 10.1016/j.tet.2015.05.022
70. N. V. Rostovskii, P. A. Sakharov, M. S. Novikov, A. F. Khlebnikov, G. L. Starova. Cu(I)-NHC-Catalyzed (2+3)-Annulation of Tetramic Acids with 2H-Azirines: Stereoselective Synthesis of Functionalized Hexahydropyrrolo[3,4-b]pyrroles. Org. Lett. 2015, 17, 4148–4151. DOI: 10.1021/acs.orglett.5b01883
71. N. V. Rostovskii, M. S. Novikov, A. F. Khlebnikov, V. A. Khlebnikov, S. M. Korneev. Rh(II)-carbenoid mediated 2H-azirine ring-expansion as a convenient route to non-fused photo- and thermochromic 2H-1,4-oxazines. Tetrahedron 2013, 69, 4292–4301. DOI: 10.1016/j.tet.2013.03.106
72. N. V. Rostovskii, M. S. Novikov, A. F. Khlebnikov, S. M. Korneev, D. S. Yufit. Cu(II)-catalyzed domino reaction of 2H-azirines with diazotetramic and diazotetronic acids. Synthesis of 2-substituted 2H-1,2,3-triazoles. Org. Biomol. Chem. 2013, 11, 5535–5545. DOI: 10.1039/c3ob40708j
73. M. S. Novikov, I. A. Smetanin, A. F. Khlebnikov, N. V. Rostovskii, D. S. Yufit. Synthesis of electron-poor 4-halo-2-azabuta-1,3-dienes by Rh(II)-catalyzed diazo ester-azirine coupling. 2-Azabuta-1,3-diene-2,3-dihydroazete valence isomerism. Tetrahedron Lett. 2012, 53, 5777–5780. DOI: 10.1016/j.tetlet.2012.08.063
74. V. A. Khlebnikov, M. S. Novikov, A. F. Khlebnikov, N. V. Rostovskii. Rh(II)-Catalyzed reactions of 2H-azirines with ethyl 2-acyl-2-diazoacetates. Synthesis of novel photochromic oxazines. Tetrahedron Lett. 2009, 50, 6509–6511. DOI 10.1016/j.tetlet.2009.09.033

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