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Научная группа профессора В.П. Толстого

Обновлено

Научная группа кафедры химии твердого тела

Программируемый послойный синтез функциональных наноматериалов в условиях «мягкой химии»

Состав научной группы

  • Толстой Валерий Павлович, профессор, доктор химических наук.
  • Гулина Лариса Борисовна, старший научный сотрудник, кандидат химических наук.
  • Лобинский Артем Анатольевич, научный сотрудник, кандидат химических наук.
  • Кукло Леонид Игоревич, инженер, кандидат химических наук.
  • Попков Вадим Игоревич, научный сотрудник, участник программы постдоков СПбГУ, кандидат химических наук.
  • Канева Мария Вячеславовна, аспирант.
  • Гуренко Владислав Евгеньевич, магистрант.
  • Владимирова Надежда Игоревна, магистрант.
  • Левшакова Александра Сергеевна, магистрант.
  • Стрыканова Вера Владимировна, бакалавр.

Темы научной работы

1. Создание новых маршрутов синтеза мультислоёв гибридных неорганических и органических соединений и получение функциональных наноматериалов на их основе

htt Tolstoy VPРуководитель темы профессор, доктор химических наук Толстой Валерий Павлович.

tols 3 tols 2 tols 1

2. Синтез наноразмерных кристаллов неорганических соединений с участием химических реакций на границе раздела газ-жидкость

htt GulinaРуководитель темы старший научный сотрудник, кандидат химических наук Гулина Лариса Борисовна.

guli 1 guli 2 guli 3

3. Программируемый послойный синтез мультислоев оксидов переходных металлов и создание новых электродных наноматериалов для электрохимической и водородной энергетики

htt Lobinsky AAРуководитель темы научный сотрудник, кандидат химических наук Лобинский Артем Анатольевич.

lobi 1 lobi 2 lobi 3

4. Разработка новых высокопроизводительных автоматизированных установок для послойного синтеза наноразмерных структур

htt Kuklo LIРуководитель темы инженер-исследователь, кандидат химических наук Кукло Леонид Игоревич.

kuk 1 kuk 2

5. Новые функциональные наноматериалы на основе сложных оксидов железа, синтезированных методами ионного и ионно-коллоидного наслаивания

htt Popkov VIРуководитель темы научный сотрудник, участник программы постдоков СПбГУ, кандидат химических наук Попков Вадим Игоревич.

popk 1 popk 2

Последние публикации

2019 год

  1. Tolstoy, V.P., Kuklo, L.I., Gulina, L.B., Ni(II) doped FeOOH 2D nanocrystals, synthesized by Successive Ionic Layer Deposition, and their electrocatalytic properties during oxygen evolution reaction upon water splitting in the alkaline medium (2019) Journal of Alloys and Compounds, 786, pp. 198-204. DOI: 10.1016/j.jallcom.2019.01.324
  2. Popkov, V.I., Tolstoy, V.P., Omarov, S.O., Nevedomskiy, V.N., Enhancement of acidic-basic properties of silica by modification with CeO2 -Fe2O3 nanoparticles via successive ionic layer deposition (2019) Applied Surface Science, 473, pp. 313-317. DOI: 10.1016/j.apsusc.2018.12.129
  3. Tolstoy, V.P., Gulina, L.B., Golubeva, A.A., Ermakov, S.S., Gurenko, V.E., Navolotskaya, D.V., Vladimirova, N.I., Koroleva, A.V. Thin layers formed by the oriented 2D nanocrystals of birnessite-type manganese oxide as a new electrochemical platform for ultrasensitive nonenzymatic hydrogen peroxide detection (2019) Journal of Solid State Electrochemistry, 23 (2), pp. 573-582. DOI: 10.1007/s10008-018-04165-6
  4. Lobinsky, A.A., Tolstoy, V.P., Synthesis of CoAl-LDH nanosheets and N-doped graphene nanocomposite via Successive Ionic Layer Deposition method and study of their electrocatalytic properties for hydrogen evolution in alkaline media (2019) Journal of Solid State Chemistry, 270, pp. 156-161. DOI: 10.1016/j.jssc.2018.09.041
  5. Laptenkova, A.V., Tolstoy, V.P., Selyutin, A.A., Layer-by-layer synthesis of ferrocyanides of transition metals, as a new method of controlled self-assembly of cathodic materials (2019) AIP Conference Proceedings, 2064, статья № 030008. DOI: 10.1063/1.5087670
  6. Kodinzev, I., Lobinsky, A., Tolstoy, V., Successive ionic layer deposition of NiPx nanolayers on the surface of nickel foam and their electrocatalytic properties for oxygen evolution reaction upon water splitting in alkaline medium (2019) AIP Conference Proceedings, 2064, статья № 030005, DOI: 10.1063/1.5087667
  7. Gulina, L.B., Schikora, M., Privalov, A.F., Weigler, M., Tolstoy, V.P., Murin, I.V., Vogel, M. Influence of Morphology of LaF3 Nano-crystals on Fluorine Dynamics Studied by NMR Diffusometry (2019) Applied Magnetic Resonance, Article in Press. DOI: 10.1007/s00723-018-1077-z
  8. V.P.Tolstoy, A.A.Lobinsky, M.V.Kaneva, Features of inorganic nanocrystals formation in conditions of successive ionic layers deposition in water solutions and the Co(II)Co(III) 2D layered double hydroxide synthesis, Journal of Molecular Liquids, 2019, accepted manuscript, https://doi.org/10.1016/j.molliq.2019.02.067

2018 год

  1. Gulina, L.B., Tolstoy, V.P., Lobinsky, A.A., Petrov, Y.V. Formation of Fe and Fe2O3 Microspirals via Interfacial Synthesis (2018) Particle and Particle Systems Characterization, 35 (9), статья № 1800186, DOI: 10.1002/ppsc.201800186
  2. Gulina, L.B., Tolstoy, V.P., Petrov, Y.V., Danilov, D.V. Interface-Assisted Synthesis of Single-Crystallрine ScF3 Microtubes (2018) Inorganic Chemistry, 57 (16), pp. 9779-9781. DOI: 10.1021/acs.inorgchem.8b01375
  3. Gulina, L.B., Tolstoy, V.P., Kasatkin, I.A., Fateev, S.A. Flower-like silver nanocrystals: facile synthesis via a gas–solution interface technique (2018) Journal of Materials Science, 53 (11), pp. 8161-8169. DOI: 10.1007/s10853-018-2164-0
  4. Gulina, L., Tolstoy, V., Kuklo, L., Mikhailovskii, V., Panchuk, V., Semenov, V. Synthesis of Fe(OH)3 Microtubes at the Gas–Solution Interface and Their Use for the Fabrication of Fe2O3 and Fe Microtubes (2018) European Journal of Inorganic Chemistry, 2018 (17), pp. 1842-1846. DOI: 10.1002/ejic.201800182
  5. Lobinsky, A.A., Tolstoy, V.P. Synthesis of 2D Zn-Co LDH nanosheets by a successive ionic layer deposition method as a material for electrodes of high-performance alkaline battery-supercapacitor hybrid devices (2018) RSC Advances, 8 (52), pp. 29607-29612. DOI: 10.1039/c8ra00671g
  6. A. A. Lobinsky, V. P. Tolstoy, I. A. Kodinzev, Electrocatalytic properties of NiOOH nanolayers, synthesized by successive ionic layer deposition, during the oxygen evolution reaction upon water splitting in the alkaline medium Nanosystems: Physics, Chemistry, Mathematics, 2018, 9 (5), P. 669–675, DOI 10.17586/22208054201895669675
  7. Kasatkin, I.A., Gulina, L.B., Platonova, N.V., Tolstoy, V.P., Murin, I.V. Strong negative thermal expansion in the hexagonal polymorph of ScF3 (2018) CrystEngComm, 20 (20), pp. 2768-2771. DOI: 10.1039/c8ce00257f

2017 год

  1. Gulina, L.B., Tolstoy, V.P., Tolstobrov, E.V. Facile synthesis of 2D silver nanocrystals by a gas–solution interface technique (2017) Mendeleev Communications, 27 (6), pp. 634-636. DOI: 10.1016/j.mencom.2017.11.033
  2. Kodintsev, I., Tolstoy, V., Lobinsky, A. Room temperature synthesis of composite nanolayer consisting of AgMnO2 delafossite nanosheets and Ag nanoparticles by successive ionic layer deposition and their electrochemical properties (2017) Materials Letters, 196, pp. 54-56. DOI: 10.1016/j.matlet.2017.02.130
  3. Lobinsky, A.A., Tolstoy, V.P. Synthesis of γ-MnOOH nanorods by successive ionic layer deposition method and their capacitive performance (2017) Journal of Energy Chemistry, 26 (3), pp. 336-339. DOI: 10.1016/j.jechem.2017.04.015
  4. Tolstoy, V.P., Kodintsev, I.A., Reshanova, K.S., Lobinsky, A.A. A brief review of metal oxide (hydroxide)-graphene nanocomposites synthesis by layer-by-layer deposition from solutions and synthesis of CuO nanorods-graphene nanocomposite (2017) Reviews on Advanced Materials Science, 49 (1), pp. 28-37.
  5. Gulina, L.B., Tolstoy, V.P., Kasatkin, I.A., Murin, I.V. Facile synthesis of scandium fluoride oriented single-crystalline rods and urchin-like structures by a gas-solution interface technique (2017) CrystEngComm, 19 (36), pp. 5412-5416. DOI: 10.1039/c7ce01396e
  6. V. E. Gurenko, V. P. Tolstoy, L. B. Gulina, The effect of microtube formation with walls, containing Fe3O4 nanoparticles, via gassolution interface technique by hydrolysis of the FeCl2 and FeCl3 mixed solution with gaseous ammonia, Nanosystems: Physics, Chemistry, Mathematics, 2017, 8 (4), P. 471–475
  7. Gulina, L.B., Tolstoy, V.P., Kasatkin, I.A., Kolesnikov, I.E., Danilov, D.V. Formation of oriented LaF3 and LaF3:Eu3+ nanocrystals at the gas − Solution interface (2017) Journal of Fluorine Chemistry, 200, pp. 18-23. DOI: 10.1016/j.jfluchem.2017.05.006

2016 год

  1. Gulina, L.B., Tolstoy, V.P., Lobinsky, A.A., Petrov, Y.V. The interaction of gaseous SiF4 and HF with surface of aqueous solution of LaCl3 leading to the formation of the LaF3–SiO2·nH2O nanocomposite and microtubes on its basis (2016) Russian Journal of General Chemistry, 86 (12), pp. 2689-2692. DOI: 10.1134/S1070363216120197
  2. Kodintsev, I., Reshanova, K., Tolstoy, V. Layer-by-layer synthesis of metal oxide (or hydroxide)-graphene nanocomposites. the synthesis of CuO nanorods-graphene nanocomposite (2016) AIP Conference Proceedings, 1748, статья № 040005, DOI: 10.1063/1.4954357
  3. Lobinsky, A.A., Tolstoy, V.P., Gulina, L.B. A novel oxidation-reduction route for successive ionic layer deposition of NiO1+x·nH2O nanolayers and their capacitive performance (2016) Materials Research Bulletin, 76, pp. 229-234. DOI: 10.1016/j.materresbull.2015.12.023
  4. Kuklo, L.I., Belyaninova, S.I., Ermakov, S.S., Tolstoy, V.P. Fe0.5MnOx · nH2O nanolayers synthesized via successive ionic layer deposition and their use in voltammetric nonenzymatic determination of hydrogen peroxide (2016) Nanotechnologies in Russia, 11 (3-4), pp. 137-143. DOI: 10.1134/S1995078016020105
  5. Kuklo, L.I., Tolstoy, V.P. Redox reactions involving Ce3+ cations and FeO 4 2- anions and the synthesis of Ce1.1FeO x ·nH2O nanolayers by the SILD method (2016) Russian Journal of General Chemistry, 86 (1), pp. 1-4. DOI: 10.1134/S1070363216010011
  6. Ermakov, S.S., Nikolaev, K.G., Tolstoy, V.P. Novel electrochemical sensors with electrodes based on multilayers fabricated by layer-by-layer synthesis and their analytical potential (2016) Russian Chemical Reviews, 85 (8), pp. 880-900. DOI: 10.1070/RCR4605
  7. Gulina, L.B., Schäfer, M., Privalov, A.F., Tolstoy, V.P., Murin, I.V., Vogel, M. Synthesis and NMR investigation of 2D nanocrystals of the LaF3doped by SrF2 (2016) Journal of Fluorine Chemistry, 188, pp. 185-190. DOI: 10.1016/j.jfluchem.2016.07.006
  8. Gulina, L.B., Pchelkina, A.A., Nikolaev, K.G., Navolotskaya, D.V., Ermakov, S.S., Tolstoy, V.P. A brief review on immobilization of gold nanoparticles on inorganic surfaces and Successive Ionic Layer Deposition (2016) Reviews on Advanced Materials Science, 44 (1), pp. 46-53.

Гранты

РНФ, РФФИ, СПбГУ, INTAS (Россия, Франция, Украина, Италия), CRDF (США, Молдова), Haldor Topsoe A/G (Дания)