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Боярский Вадим Павлович

Опубликовано в Личные страницы 09.01.2017

д.х.н. (2010), профессор Вадим Павлович Боярский

Кафедра физической органической химии, комната 4162

Тел.: (раб.) +7(812)3241270, (моб.) +7(921)9154284

e-mail: v.boiarskii@spbu.ru

Почтовый адрес: Институт химии СПбГУ
Университетский пр., д. 26, 198504 Санкт-Петербург, Россия

2010–… профессор кафедры физической органической химии ИХ СПбГУ

2013–… заместитель главного редактора Журнала общей химии

1997–2010 доцент кафедры физической органической химии ИХ СПбГУ

2007–2013 приглашенный исследователь в группе проф. С. Хелла (Нобелевский лауреат 2014), Институт биофизической химии общества Макса Планка, Геттеинген, Германия

1994–1997 ст. н. с. кафедры физической органической химии ИХ СПбГУ

1990–1994 н. с. лаборатории галогенароматических углеводородов ВНИИ «Нефтехим»

1986–1989 аспирантура ВНИИ «Нефтехим»

1981–1986 обучение на химическом факультете ЛГУ

Преподавание

  • Гомогенный металлокомплексный катализ (магистратура; 34 часа)
  • Теоретические основы органической химии (бакалавриат; 60 часов)
  • Химическая связь в органических соединениях (бакалавриат; 26 часов)

Избранные публикации

  1. Alexander S. Mikherdov, Mikhail A. Kinzhalov, Alexander S. Novikov, Vadim P. Boyarskiy, Irina A. Boyarskaya, Dmitry V. Dar’in, Galina L. Starova, Vadim Yu. Kukushkin. Difference in Energy between Two Distinct Types of Chalcogen Bonds Drives Regioisomerization of Binuclear (Diaminocarbene)PdII Complexes. J. Am. Chem. Soc., 2016, 138, 14129−14137.
  2. V. A. Rassadin, D. P. Zimin, G. Z. Raskil’dina, A. Yu. Ivanov, V. P. Boyarskiy, S. S. Zlotskii, V. Yu. Kukushkin. Solvent- and Halide-free Synthesis of Pyridine-2-yl Substituted Ureas through Facile C–H Functionalization of Pyridine N-oxides. Green Chem., 2016, 28, 6630–6636.
  3. V. P. Boyarskiy, D. S. Ryabukhin, N. A. Bokach, A. V. Vasilyev. Alkenylation of Arenes and Heteroarenes with Alkynes. Chem. Rev., 2016, 116, 5894−5986.
  4. M. A. Kinzhalov, S. A. Timofeeva, K. V. Luzyanin, V. P. Boyarskiy, A. A. Yakimanskiy, M. Haukka, V. Yu. Kukushkin. Palladium(II)-mediated addition of benzenediamines to isocyanides. Generation of three types of diaminocarbene ligands depending on isomeric structure of the nucleophile. Organometallics, 2016, 35(2), 218–228.
  5. Valentin A. Rassadin, Vadim P. Boyarskiy, Vadim Yu. Kukushkin. Facile gold-catalyzed heterocyclization of terminal alkynes and cyanamides leading to substituted 2-amino-1,3-oxazoles. Org. Lett., 2015, 17(14), 3502–3505.
  6. Svetlana A. Timofeeva, Mikhail A. Kinzhalov, Elena A. Valishina, Konstantin V. Luzyanin, Vadim P. Boyarskiy, Tatyana M. Buslaeva, Matti Haukka, Vadim Yu. Kukushkin. Application of palladium complexes bearing acyclic amino(hydrazido)carbene ligands as catalysts for copper-free Sonogashira cross-coupling. J. Catalysis, 2015, 329, 449–456.
  7. V. P. Boyarskiy, N. A. Bokach, K. V. Luzyanin, V. Yu. Kukushkin. Metal-Mediated and Metal-Catalyzed Reactions of Isocyanides. Chem. Rev., 2015, 115(7), 2698–2779.
  8. Boyarskiy, V. P.; Luzyanin, K. V.; Kukushkin, V. Y., Palladium-(acyclic diaminocarbene) species as alternative to palladium-(nitrogen heterocyclic carbenes) in cross-coupling catalysis, in Advances in organometallic chemistry and catalysis: the Silver/Gold jubilee International Conference on Organometallic Chemistry celebratory book; Pombeiro, A. J. L., Ed.; John Wiley & Sons, Inc., 2014, pp. 145–156.
  9. V. N. Belov, G. Yu. Mitronova, M. L. Bossi, V. P. Boyarskiy, E. Hebisch, C. Geisler, K. Kolmakov, C. A. Wurm, K. I. Willig, S. W. Hell. Masked Rhodamine Dyes of Five Principal Colors Revealed by Photolysis of a 2-Diazo-1-Indanone Caging Group: Synthesis, Photophysics, and Light Microscopy Applications. Chem. Eur. J., 2014, 20(41), 13162–13173.
  10. K. Kolmakov, C. A. Wurm, D. N. H. Meineke, F. Goettfert, V. P. Boyarskiy, V. N. Belov, S. W. Hell. Polar Red-Emitting Rhodamine Dyes with Reactive Groups: Synthesis, Photophysical Properties, and Two-Color STED Nanoscopy Applications. Chem. Eur. J., 2014, 20, 146–157.
  11. Mikhail A. Kinzhalov, Vadim P. Boyarskiy, Konstantin V. Luzyanin, Matti Haukka, Vadim Yu. Kukushkin. ADC-Based palladium catalysts for aqueous Suzuki–Miyaura cross-coupling exhibit greater activity than the most advantageous catalytic systems. Organometallics, 2013, 32(18), 5212−5223.
  12. Mikhail A. Kinzhalov, Vadim P. Boyarskiy, Konstantin V. Luzyanin, Fedor M. Dolgushin, Vadim Yu. Kukushkin. Metal-Mediated Coupling of a Coordinated Isocyanide and Indazoles. Dalton Trans., 2013, 42(29), 10394–10397.
  13. V. P. Boyarskiy, K. V. Luzyanin, V. Yu. Kukushkin. Acyclic Diaminocarbenes (ADCs) as a Promising Alternative to N-Heterocyclic Carbenes (NHCs) in Transition Metal Catalyzed Organic Transformations. Coord. Chem. Rev., 2012, 256(17–18), 2029–2056.
  14. A. Muthukrishnan, V. Boyarskiy, M. V. Sangaranarayanan, I. Boyarskaya. Mechanism and Regioselectivity of the Electrochemical Reduction in Polychlorobiphenyls (PCBs): Kinetic Analysis for the Successive Reduction of Chlorines from Dichlorobiphenyls. J. Phys. Chem. C, 2012, 116(1), 655–664.
  15. V. N. Belov, C. A. Wurm, V. P. Boyarskiy, S. Jakobs, S. W. Hell. Rhodamines NN: A Novel Class of Caged Fluorescent Dyes. Angewandte Chemie Int. Ed. 2010, 49(20), 35203523.
  16. Vladimir N. Belov, Mariano L. Bossi, Jonas Fölling, Vadim P. Boyarskiy, Stefan W. Hell Rhodamine Spiroamides for Multicolor Single-Molecule Switching Fluorescent Nanoscopy. Chemistry-A European Journal, 2009, 15(41), 10762–10776.
  17. Mariano Bossi, Jonas Fölling, Vladimir N. Belov, Vadim P. Boyarskiy, Rebecca Medda, Alexander Egner, Christian Eggeling, Andreas Schönle, Stefan W. Hell. Multicolor Far-Field Fluorescence Nanoscopy through Isolated Detection of Distinct Molecular Species. Nano Lett., 2008, 8(8), 2463–2468.
  18. Vadim P. Boyarskiy, Vladimir N. Belov, Rebecca Medda, Birka Hein, Mariano Bossi, Stefan W. Hell. Photostable, amino reactive and water-soluble fluorescent labels based on sulfonated rhodamine with a rigidized xanthene fragment. Chemistry-A European Journal 2008, 14(6), 1784–1792.

Ответственный за содержание: Роман Зумберов, r.zumberov@spbu.ru